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Excitation-emission matrix (EEM) fluorescence spectroscopy for characterization of organic matter in

Jinlan Yu, Kang Xiao, Wenchao Xue, Yue-xiao Shen, Jihua Tan, Shuai Liang, Yanfen Wang, Xia Huang

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 2, doi: 10.1007/s11783-019-1210-8

Abstract: • Principles and methods for fluorescence EEM are systematically outlined. • Fluorophore peak/region/component and energy information can be extracted from EEM. • EEM can fingerprint the physical/chemical/biological properties of DOM in MBRs. • EEM is useful for tracking pollutant transformation and membraneThree-dimensional excitation-emission matrix (3D-EEM) fluorescence spectroscopy, a powerful tool forapplying EEM to characterize DOM in MBR studies.

Keywords: excitation-emission matrix (EEM)     dissolved organic matter (DOM)     membrane bioreactor (MBR)     fluorescence    

Identification of sources, characteristics and photochemical transformations of dissolved organic matter with EEM-PARAFAC

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 5, doi: 10.1007/s11783-020-1340-z

Abstract:

• The source of DOM in surface water and sediment is inconsistent.

Keywords: Dissolved organic matter     Parallel factor analysis     Excitation-emission matrices     Photodegradation    

A chemometric analysis on the fluorescent dissolved organic matter in a full-scale sequencing batch reactor for municipal wastewater treatment

Chen Qian, Wei Chen, Wei-Hua Li, Han-Qing Yu

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 4, doi: 10.1007/s11783-017-0962-2

Abstract: Fluorescence excitation-emission matrix (EEM) in combination with parallel factor analysis (PARAFAC)The results suggest that use of PARAFAC may cause confusion in selecting the component number, while EEM-PFFCA

Keywords: Wastewater treatment plants (WWTPs)     Excitation-emission matrix (EEM)     Parallel factor (PARAFAC)     Parallel    

Interactions between metal ions and the biopolymer in activated sludge: quantification and effects of system pH value

Yun Zhou, Siqing Xia, Binh T. Nguyen, Min Long, Jiao Zhang, Zhiqiang Zhang

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 1, doi: 10.1007/s11783-017-0898-6

Abstract: The biopolymer showed two protein-like fluorescence peaks (peaks A and B). Interactions of Pb(II) and biopolymer were quantified at various system pH values. System pH values significantly affect the quenching constant values for both peaks. Peak B plays a more important role in the interactions than peak A. Removal mechanism of metal ions by activated sludge system was further disclosed. The quantification and effects of system pH value on the interactions between Pb(II) and the biopolymer from activated sludge were investigated. The biopolymer had two protein-like fluorescence peaks (Ex/Em= 280 nm/326–338 nm for peak A; Ex/Em= 220–230 nm/324–338 nm for peak B). The fluorescence intensities of peak B were higher than those of peak A. The fluorophores of both peaks could be largely quenched by Pb(II), and the quencher dose for peak B was about half of that for peak A. The modified Stern-Volmer equation well depicted the fluorescence quenching titration. The quenching constant (Ka) values for both peaks decreased with rising system pH value, and then sharply decreased under alkaline conditions. It could be attributed to that the alkaline conditions caused the reduction of available Pb(II) due to the occurrence of Pb(OH)2 sediments. The Ka values of peak B were bigger than those for peak A at the same system pH values. Accordingly, the aromatic protein (peak B) plays the key role in the interactions between metal ions and the biopolymer.

Keywords: Metal ions     Biopolymer     Activated sludge     Three-dimensional excitation emission matrix (3D-EEM)     Fluorescence    

Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh/γ-Al

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 428-434 doi: 10.1007/s11783-013-0517-0

Abstract: catalysts were thoroughly measured using transmission electron microscopy (TEM), three-dimensional excitation-emissionfluorescent matrix (EEFM) spectroscopy, UV-Vis absorption, dynamic light-scattering (DLS), zeta potentialspectroscopy was proven to be an appropriate and effective method to characterize the Pt clusters in intrinsic emission

Keywords: ammonia (NH3)     nanosized Pt-Rh/γ-Al2O3 catalyst     excitation-emission fluorescentmatrix (EEFM)     selective catalytic oxidation (SCO)     tubular fixed-bed reactor (TFBR)    

Chemical identification and genotoxicity analysis of petrochemical industrial wastewater

Jing ZHANG, Shigong WANG, Can WANG, Hongying HU

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 3,   Pages 350-359 doi: 10.1007/s11783-012-0404-0

Abstract: The actual harmful effects of industrial wastewater can not be reflected by the conventional water quality index. Therefore, the change in dissolved organic matter and the genetic toxicity of petrochemical wastewater were observed in the current study by examining the wastewater treatment plant of a large petrochemical enterprise in Northwest China. Using XAD-8, MSC, and DA-7 resins, the wastewater was separated into six fractions, namely, hydrophobic acid (HOA), hydrophobic neutral (HOB), hydrophobic alkaline, hydrophilic acid, hydrophilic alkaline, and hydrophilic neutral. Umu-test was used to detect the genetic toxicity of the wastewater samples, and fluorescence spectra were also obtained to examine genetic toxic substances. The results show that wastewater treatment facilities can effectively reduce the concentration of organic matter in petrochemical wastewater ( <0.05). However, the mixing of aniline wastewater can increase the amount of organic carbon ( <0.05) and can overload facilities. This finding shows that the mixed collection and joint treatment of different types of petrochemical wastewater can affect the water quality of the effluent. Particularly, hydrophobic substances can be difficult to remove and account for a relatively large proportion of the effluent. The mixture of aniline wastewater can increase the genetic toxicity of the effluent ( <0.05), and biologic treatment can not effectively decrease the toxicity. Most of the genetic toxicology may exist in the HOA and HOB fractions. Fluorescence spectroscopy also confirms this result, and tryptophan-like substances may play an important role in genetic toxicity.

Keywords: dissolved organic matter     resin fraction     genetic toxicity     fluorescence excitation and emission matrix    

Characterization of the dissolved organic matter in sewage effluent of sequence batch reactor: the impact of carbon source

Jin GUO, Feng SHENG, Jianhua GUO, Xiong YANG, Mintao MA, Yongzhen PENG

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 2,   Pages 280-287 doi: 10.1007/s11783-011-0336-0

Abstract: Size exclusion chromatography (SEC) and fluorescence of excitation emission matrices (EEM) demonstratedThe DOC fractionation and the EEM all demonstrated that EfOM from the effluent of the SBR fed with starch

Keywords: extracellular polymeric substance (EPS)     molecular weight distribution (MWD)     hydrophobic     hydrophilic     excitationemission matrices (EEM)    

Approximation of structural damping and input excitation force

Mohammad SALAVATI

Frontiers of Structural and Civil Engineering 2017, Volume 11, Issue 2,   Pages 244-254 doi: 10.1007/s11709-016-0371-9

Abstract: Structural dynamic characteristics are the most significant parameters that play a decisive role in structural damage assessment. The more sensitive parameter to the damage is the damping behavior of the structure. The complexity of structural damping mechanisms has made this parameter to be one of the ongoing research topics. Despite all the difficulties in the modeling of damping, there are some approaches like as linear and nonlinear models which are described as the energy dissipation throughout viscous, material or structural hysteretic and frictional damping mechanisms. In the presence of a mathematical model of the damping mechanisms, it is possible to estimate the damping ratio from the theoretical comparison of the damped and un-damped systems. On the other hand, solving the inverse problem of the input force estimation and its distribution to each SDOFs, from the measured structural responses plays an important role in structural identification process. In this paper model-based damping approximation method and a model-less structural input estimation are considered. The effectiveness of proposed methods has been carried out through analytical and numerical simulation of the lumped mass system and the results are compared with reference data. Consequently, high convergence of the comparison results illustrates the satisfactory of proposed approximation methods.

Keywords: structural modal parameters     damping identification method     input excitation force identification     Inverse    

Decellularized extracellular matrix mediates tissue construction and regeneration

Frontiers of Medicine 2022, Volume 16, Issue 1,   Pages 56-82 doi: 10.1007/s11684-021-0900-3

Abstract: Contributing to organ formation and tissue regeneration, extracellular matrix (ECM) constituents provideContaining the crucial traits of the cellular microenvironment, ECM substitutes mediate cell–matrix interactions

Keywords: decellularized extracellular matrix     3D culture     organoids     tissue repair    

Simulation Research on PWM Control in Excitation System of Generator

Jia Guixi,Xu Wei,Guo Baoyue,Zhang Chentang

Strategic Study of CAE 2005, Volume 7, Issue 6,   Pages 50-53

Abstract:

A high quality excitation system not only plays an important role in the stability of power systemIn this paper, a PWM rectifier is applied to excitation system of synchronous generators.;s supply by achieving low harmonic current conversion and improving high power factor transform of excitation

Keywords: PWM     high power factor     excitation system     Matlab simulation    

Perspective of mixed matrix membranes for carbon capture

Shinji Kanehashi, Colin A. Scholes

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 3,   Pages 460-469 doi: 10.1007/s11705-019-1881-5

Abstract: Mixed matrix membranes (MMMs) have a composite structure that consists of polymers and fillers, therefore

Keywords: membranes     polymeric     mixed matrix     impurities    

A subband excitation substitute based scheme for narrowband speech watermarking Article

Wei LIU, Ai-qun HU

Frontiers of Information Technology & Electronic Engineering 2017, Volume 18, Issue 5,   Pages 627-643 doi: 10.1631/FITEE.1601503

Abstract: imposed on a passband watermark signal by forcing its power level to be the same as the original passband excitation

Keywords: Analysis filter     Linear prediction     Narrowband speech watermarking     Passband excitation replacement    

A new prediction method of industrial atmospheric pollutant emission intensity based on pollutant emission

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 1, doi: 10.1007/s11783-023-1608-1

Abstract:

● Established a quantification method of pollutant emission standard

Keywords: Industrial atmospheric pollutants     Pollutant emission standards     Quantitative method     Machine learning    

Strengthening of reinforced concrete beams using fiber-reinforced cementitious matrix systems fabricated

Frontiers of Structural and Civil Engineering   Pages 1100-1116 doi: 10.1007/s11709-023-0967-9

Abstract: The performance of a new fiber-reinforced cementitious matrix (FRCM) system developed using custom-designed

Keywords: fiber-reinforced cementitious matrix     flexural strengthening     shear strengthening     carbon fiber-reinforced    

A dynamic model of mobile concrete pump boom based on discrete time transfer matrix method

Wu REN, Yunxin WU, Zhaowei ZHANG

Frontiers of Mechanical Engineering 2013, Volume 8, Issue 4,   Pages 360-366 doi: 10.1007/s11465-013-0280-8

Abstract: A dynamics model of a mobile concrete pump boom is established based on discrete time transfer matrixThe overall dynamic equation and transfer matrix of the model can be assembled by sub-structures A and

Keywords: multi-body     mobile concrete pump boom     discrete time transfer matrix method (DTTMM)     kinematic     dynamic     tip    

Title Author Date Type Operation

Excitation-emission matrix (EEM) fluorescence spectroscopy for characterization of organic matter in

Jinlan Yu, Kang Xiao, Wenchao Xue, Yue-xiao Shen, Jihua Tan, Shuai Liang, Yanfen Wang, Xia Huang

Journal Article

Identification of sources, characteristics and photochemical transformations of dissolved organic matter with EEM-PARAFAC

Journal Article

A chemometric analysis on the fluorescent dissolved organic matter in a full-scale sequencing batch reactor for municipal wastewater treatment

Chen Qian, Wei Chen, Wei-Hua Li, Han-Qing Yu

Journal Article

Interactions between metal ions and the biopolymer in activated sludge: quantification and effects of system pH value

Yun Zhou, Siqing Xia, Binh T. Nguyen, Min Long, Jiao Zhang, Zhiqiang Zhang

Journal Article

Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh/γ-Al

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

Journal Article

Chemical identification and genotoxicity analysis of petrochemical industrial wastewater

Jing ZHANG, Shigong WANG, Can WANG, Hongying HU

Journal Article

Characterization of the dissolved organic matter in sewage effluent of sequence batch reactor: the impact of carbon source

Jin GUO, Feng SHENG, Jianhua GUO, Xiong YANG, Mintao MA, Yongzhen PENG

Journal Article

Approximation of structural damping and input excitation force

Mohammad SALAVATI

Journal Article

Decellularized extracellular matrix mediates tissue construction and regeneration

Journal Article

Simulation Research on PWM Control in Excitation System of Generator

Jia Guixi,Xu Wei,Guo Baoyue,Zhang Chentang

Journal Article

Perspective of mixed matrix membranes for carbon capture

Shinji Kanehashi, Colin A. Scholes

Journal Article

A subband excitation substitute based scheme for narrowband speech watermarking

Wei LIU, Ai-qun HU

Journal Article

A new prediction method of industrial atmospheric pollutant emission intensity based on pollutant emission

Journal Article

Strengthening of reinforced concrete beams using fiber-reinforced cementitious matrix systems fabricated

Journal Article

A dynamic model of mobile concrete pump boom based on discrete time transfer matrix method

Wu REN, Yunxin WU, Zhaowei ZHANG

Journal Article